Following are good links Xpath in BizTalk , Original Article is here
- Common XPATH Examples, Questions, Issues with Biztalk

- Using XPath Inside BizTalk Orchestrations

- BizTalk Working With XPath – XPath 1.0 Function Library Quick Reference

- XPath – the hidden language of BizTalk?

- BizTalk 2010 Recipes : Orchestrations – Using XPath Queries on Messages

- BizTalk Server: Handling decimal types with the xpath() Function

- BizTalk: xpath: How to work with empty and Null elements in Orchestration
